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Beilstein J. Org. Chem. 2013, 9, 1285–1295, doi:10.3762/bjoc.9.145
Graphical Abstract
Scheme 1: Proposed mechanisms for the formation of fullerenol anions and distonic radical anions observed by ...
Figure 1: Negative-ion mass spectra for a 0.5 × 10−5 M solution of C60(OH)24 in ultrapure water: (a) full sca...
Scheme 2: Examples of proposed structures for the main deprotonated molecules and final distonic molecular io...
Scheme 3: Proposed (−)ESI-MS ionization mechanisms for fullerenol C60(OH)24 in pure water.
Figure 2: Negative-ion mass spectra of a 0.5 × 10−5 M aqueous solution of C60(OH)24 in ammonia solution: (a) ...
Figure 3: Positive ionization ESI mass spectrum of C60(OH)24 in (a) 3 × 10−1 M (b) 2 × 10−2 M aqueous ammonia...
Scheme 4: Proposed (+)ESI-MS ionization mechanisms for fullerenol C60(OH)24 in ammonia solution.